Substituted imidazoles and triazoles

Details Substituted imidazoles and triazoles Substituted imidazoles and triazoles

C - Chemistry, Metallurgy

07

D

260/305, 167/9,

C07D 405/06 (2006.01) A01N 43/50 (2006.01) A01N 43/653 (2006.01) C07D 521/00 (2006.01)

Patent

CA 1251799

ABSTRACT OF THE DISCLOSURE A compound of the formula Image where Z and Z1 are the same or different and are oxygen, sulfur, SO, SO2, or NR3; except that Z and Z1 are not simultaneously oxygen, also, if Z or Z1 is sulfur then the other of Z and Z1 cannot be NR3; Y is nitrogen or CH; R is linear or branched C2-C12 alkylene; R1 is hydrogen, C1-C4 alkyl, benzyl or phenyl; R2 is phenyl, phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, phenylamino, benzyl, phenoxy substituted with halo, C1-C4 alkyl, C1-C4 alkoxy, nitro, cyano, trihalomethyl or mono-, di- or trihalomethoxy or phenyl substituted with halo, C1-C4 alkyl, C1-C4 alkoxy, nitro, cyano, trihalomethyl or mono-, di- or trihalomethoxy; and R3 is hydrogen or C1-C6 alkyl, is disclosed. A process for forming this compound is also taught. In the process a substituted azole compound of the formula Image where Y, R1 and R2 have the meanings given above, is reacted with a compound having the formula HZ-R-Z1H where Z, Z1, R and R3 have the meanings and restrictions given above except Z and Z1 cannot be SO or SO2. Compounds having the meanings SO or SO2 for Z or Z1 are obtained by an additional oxidation step. A process for controlling fungi employing a fungicidally effective amount of the compound of this invention is recited. A composition comprising the compound of this invention plus an inert carrier therefore is also set forth.

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