Substituted phenyl .alpha.-fluoroacrylates

Details Substituted phenyl .alpha.-fluoroacrylates Substituted phenyl .alpha.-fluoroacrylates

C - Chemistry, Metallurgy

07

C

402/101, 260/481

C07C 69/653 (2006.01) C07C 51/347 (2006.01) C07C 51/367 (2006.01) C07C 51/38 (2006.01) C07C 67/00 (2006.01) C07C 67/14 (2006.01) C08F 20/22 (2006.01) C08F 20/50 (2006.01) C08F 120/02 (2006.01) C08F 120/22 (2006.01) C08G 16/00 (2006.01)

Patent

CA 1309106

Abstract of the disclosure: Substituted phenyl .alpha.-fluoroacrylates Certain esters of .alpha.-fluoroacrylic acid are accessible by hydrolyzing .alpha.-hydroxymethyl .alpha.-fluoromalonic acid esters and subsequently decarboxylating the hydrolysis product The phenyl .alpha.-fluoroacrylates which are substituted on the phenyl radical can be prepared by hydroxymethylating dimethyl .alpha.-fluoromalonate, decarboxylating and dehydrat- ing the resulting dimethyl .alpha.-hydroxymethyl-.alpha.-fluoro- malonate and esterifying the resulting .alpha.-fluoroacrylic acid with substituted phenols. The substituted phenyl .alpha.-fluoroacrylates are colorless liquids or colorless solids which can be polymerized. They are suitable for use as a starting material for the preparation of fluorine polymers.

539539

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