Sulfonated conducting polymer-grafted carbon material for...

H - Electricity – 01 – B

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H01B 1/00 (2006.01) C08K 3/04 (2006.01) H01B 1/02 (2006.01) H01B 1/04 (2006.01) H01M 4/86 (2006.01) H01M 4/88 (2006.01) H01M 4/92 (2006.01) H01M 4/96 (2006.01) H01M 8/10 (2006.01)

Patent

CA 2486790

A composition comprising particulate carbonaceous material and a sulfonated conducting polymer containing hetero atoms. The composition can further comprise a metal. Devices comprising the composition can be constructed including supported electrocatalysts, membrane electrode assemblies, and fuel cells. A method for preparing the composition comprises oxidatively polymerizing a monomer of a conducting polymer containing hetero atoms in the presence of a carbonaceous material and sulfonating the polymer or the monomer. The method grafts the sulfonated conducting polymer to the carbonaceous material. The method can further comprise metallizing the polymer- grafted carbonaceous material.

La présente invention concerne une composition comprenant un matériau carboné particulaire et un polymère conducteur sulfoné contenant des hétéro-atomes. Cette composition peut aussi comprendre un métal. On peut construire des dispositifs comprenant cette composition, notamment des électrocatalyseurs supportés, des ensembles électrode à membrane et des piles à combustible. Un procédé de préparation de cette composition consiste à effectuer une polymérisation oxydative d'un monomère de polymère conducteur contenant des hétéro-atomes en présence d'un matériau carboné et à sulfoner ce polymère ou ce monomère. Ce procédé greffe le polymère conducteur sulfoné au matériau de carbone. Ce procédé peut aussi consister à métaliser ce matériau carboné à polymère greffé.

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