Supported fluorocarbonsulfonic acid polymers and an improved...

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B01J 31/06 (2006.01) B01J 31/10 (2006.01) B01J 37/02 (2006.01) C08F 8/36 (2006.01)

Patent

CA 1291744

SUPPORTED FLUOROCARBONSULFONIC ACID POLYMERS AND AN IMPROVED METHOD FOR THEIR PREPARATION Abstract of the Disclosure This invention discloses improved heterogeneous acid catalysts and a method for preparing these catalysts. A heterogeneous acid catalyst has been prepared by coating a carrier with an aqueous emulsion containing a fluorocarbonsulfonic acid polymer in the sulfonyl fluoride form, removing the excess water, heating to a temperature above the softening point of the polymer for a time, and then converting the polymer to the active sulfonic acid form. The substrate has pores of about 0.1 micrometers or greater and a surface area of about 20 m2/g or less.

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