Supported lead oxide catalyst in the preparation of tertiary...

C - Chemistry – Metallurgy – 07 – C

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C07C 31/12 (2006.01) C07C 29/00 (2006.01) C07C 29/132 (2006.01)

Patent

CA 2133626

USE OF SUPPORTED LEAD OXIDE CATALYST IN THE PREPARATION OF TERTIARY BUTYL ALCOHOL FROM TERTIARY BUTYL HYDROPEROXIDE ABSTRACT OF THE DISCLOSURE A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of lead oxide supported on alumina and is brought into contact with the catalyst in liquid phase with agitation under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.

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