Supported, mn sulfide promoted mo and w sulfide...

B - Operations – Transporting – 01 – J

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196/54, 252/52.I

B01J 27/047 (2006.01) B01J 37/20 (2006.01) C10G 45/00 (2006.01) C10G 45/04 (2006.01) C10G 45/08 (2006.01) C10G 49/04 (2006.01)

Patent

CA 1250562

ABSTRACT OF THE DISCLOSURE This invention relates to the preparation and use of supported, manganese sulfide promoted moly- bdenum and tungsten sulfide catalysts useful for hydroprocessing processes, particularly hydro- treating. These catalysts are prepared by heating a composite of support material and precursor salt under oxygen-free conditions and in the presence of sulfur, wherein said precursor salt contains a thiometallate anion of Mo, W or mixture thereof and a cation comprising one or more promoter metals which are chelated by at least one neutral, nitrogen- containing polydentate ligand, and wherein said promoter metal comprises Mn alone or a mixture of Mn with Co, Ni, Zn, Cu or mixture thereof.

491746

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