Supported modified ziegler-metallocene catalyst for olefin...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/60 (2006.01) B01J 31/02 (2006.01) B01J 31/14 (2006.01) B01J 31/22 (2006.01) C08F 10/00 (2006.01) C08F 10/02 (2006.01) C08F 4/659 (2006.01)

Patent

CA 2262948

A novel bimetallic catalyst was prepared from trialkyl silanol, dibutylmagnesium, alkoxy titanium chloride complex and a metallocene-alumoxane reaction product supported on silica. This catalyst can polymerize ethylene and higher olefins using triethylaluminum (TEA), diisobutylaluminum hydride (DIBAH), trimethylaluminum (TMA) and other aluminum alkyls as co-catalyst to give bimodal MWD resins suitable for premium HIC and/or HMW film applications.

Nouveau catalyseur bimétallique préparé à partir de silanol de trialkyle, de dibutylmagnésium, d'un complexe de chlorure alcoxy-titane et d'un produit de réaction métallocène-alumoxane supporté sur de la silice. Ce catalyseur peut polymériser l'éthylène et des oléfines supérieures à l'aide de triéthylaluminiun (TEA), d'hydrure de diisobutylaluminium (DIBAH), de triméthylaluminium (TMA) et d'autres alkyles d'aluminium en tant que cocatalyseurs afin de produire des résines à répartition des poids moléculaires bimodale convenant pour des applications de conteneurs ménagers et industriels réutilisables et/ou de films à poids moléculaire élevé.

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