Surface modified polyamide membrane

B - Operations – Transporting – 01 – D

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18/27, 117/88.5

B01D 13/04 (1985.01)

Patent

CA 1200158

Abstract: Surface modified, skinless, hydrophilic, micro- porous, polyamide membranes are formed by preparing a casting solution comprised of (A) a casting resin system comprised of (a) an alcohol-insoluble poly- amide resin, and (b) a cationic, water-soluble, qua- ternary ammonium, thermosetting, membrane surface modifying polymer, and (B) a solvent system in which the casting resin system is soluble; inducing nuclea- tion of the casting solution by controlled addition of a nonsolvent for the casting resin system under controlled conditions to obtain a visible precipitate of casting resin system particles, thereby forming a casting composition; spreading the casting composi- tion on a substrate to form a thin film; contacting and diluting the film of the casting composition with a liquid nonsolvent system for the casting resin system, thereby precipitating the casting resin sys- tem from the casting composition in the form of a thin, skinless, hydrophilic, surface modified, micro- porous, polyamide membrane; and washing and drying the membrane. The membranes of this invention are characterized by having fine pore ratings, the sur- face properties thereof being substantially controlled by cationic, quaternary ammonium groups of a modifying polymer thereby providing a positive zeta potential in alkaline media, and for those with moderate or low levels of surface modifying polymer present, a time to reach an effluent resistivity of 14 megaohms/cm under the Resistivity Test of 10 minutes or less. They have greatly enhanced filtration efficiency over a broad pH range with a variety of contaminants, including very fine negatively charged particles, bacteria and endotoxins.

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