Suspension polymerization of vinyl chloride

C - Chemistry – Metallurgy – 08 – F

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C08F 14/06 (2006.01) C08F 2/38 (2006.01)

Patent

CA 2077397

ABSTRACT OF THE DISCLOSURE An improvement is proposed in the method for the suspen- sion polymerization of vinyl chloride, according to which the poly- vinyl chloride resin prepared by the reaction is advantageous in respect of the low initial coloration of the shaped articles there- from even when the polymerization reaction is conducted in the presence of a monomer-soluble polymerization initiator in an amount increased with an object to accelerate the polymerization reaction for improved productivity. The improvement can be achieved by introducing a chain transfer agent such as 2-mercap- toethyl alcohol and n-hexane in an amount of 0.001 to 0.2% by weight of the monomer into the polymerization mixture at a mo- ment when conversion of the monomer into polymer is in the range from 60% to 75%.

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