C - Chemistry – Metallurgy – 07 – F
Patent
C - Chemistry, Metallurgy
07
F
C07F 17/00 (2006.01) C07C 2/86 (2006.01) C07C 13/15 (2006.01)
Patent
CA 2570152
The present invention provides a method of making fulvenes, particularly 6- aryl-6-alkylfulvenes, 6-aryl-6-alkenylfulvenes, and related compounds, by combining alkyl- or alkenyl-arylketones with magnesium cyclopentadienyl reagents in nonprotic, including ethereal, solvents. The use of these compounds in preparing bis(cyclopentadienyl)methanes and related compounds, and ansa-metallocenes, is disclosed.
La présente invention concerne un procédé de production de fulvènes, en particulier de 6-aryl-6-alkylfulvènes, de 6-aryl-6-alcénylfulvènes et de composés associés, lequel procédé consiste à combiner des alkyl- ou alcényl-arylcétones et des réactifs cyclopentadiényle-magnésium dans des solvants non protiques, y compris des solvants éthérés. Cette invention porte également sur l'utilisation de ces composés pour préparer des bis(cyclopentadiényl)méthanes et des composés associés, ainsi que des ansa-métallocènes.
Jensen Michael D.
Martin Joel L.
Smith James L.
Thorn Matthew G.
Yang Qing
Chevron Phillips Chemical Company Lp
Finlayson & Singlehurst
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