Synthesis of cis-diols from aryl silanes

C - Chemistry – Metallurgy – 08 – L

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C08L 77/00 (2006.01) C07F 7/08 (2006.01) C12P 9/00 (2006.01) C12Q 1/26 (2006.01)

Patent

CA 2485306

The present invention is related to cis-diols and biological methods of producing cis-diols. The present invention further relates to processes for subsequently converting such silane cis-diols to the more stable acetonide derivatives, as well as a process for converting silane cis-diols to the corresponding catechols and the compounds produced thereby. The present invention also provides chemical methods for the conversion of said silane cis~-diols and acetonide compounds to epoxy, saturated and otherwise modified derivatives. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that is will not be used to interpret or limit the scope or meaning of the claims.

La présente invention concerne des cis-diols et des méthodes biologiques de production de cis-diols. Cette invention a également trait à des processus de conversion subséquente de tels cis-diols de silane en dérivés d'acétonide plus stables, ainsi qu'à un processus de conversion de cis-diols de silane en catéchols associés et, enfin, aux composés ainsi produits. L'invention a aussi pour objet des procédés chimiques de conversion desdits cis-diols de silane et des composés d'acétonide en résine époxyde, en dérivés saturés et, par ailleurs, modifiés.

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