Synthesis of higher polyol fatty acid polyesters using...

C - Chemistry – Metallurgy – 07 – C

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260/483, 260/233

C07C 69/33 (2006.01) C07H 13/06 (2006.01)

Patent

CA 1218648

SYNTHESIS OF HIGHER POLYOL FATTY ACID POLYESTERS USING CARBONATE CATALYSTS ABSTRACT OF THE DISCLOSURE An improved solvent-free transesterification process for producing polyol fatty acid polyesters is disclosed. In this process, a mixture of a polyol, a fatty acid methyl, 2-methoxy ethyl or benzyl ester, an alkali metal fatty acid soap, and potassium carbonate, sodium carbonate or barium carbonate as a catalyst is heated to form a homogeneous melt. To this melt is subsequently added excess fatty acid methyl, 2-methoxy ethyl or benzyl ester, yielding the desired polyol fatty acid polyesters.

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