Synthesis of inimers and hyperbranched polymers

C - Chemistry – Metallurgy – 07 – C

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C07C 69/675 (2006.01) C07C 67/08 (2006.01) C08F 20/28 (2006.01)

Patent

CA 2665607

An inimer, and process for making same, having the following formula: wherein X = halogen, nitroxide, thioester; R = H or CH3; and R' = aliphatic, non-aliphatic, linear or branched, mesogenic, non mesogenic, chiral, achiral, hydrocarbon, non-hydrocarbon, selected from fluorocarbon, oligo(oxyethylene) and siloxane substituents, alkyl, aryl, mesogenic group, non-mesogenic group, aliphatic, non-aliphatic, siloxane, perfluoroalkyl, perfluoroaryl, or other fluorocarbon group, and polymers, and the process of making them, from the inimer.

L'invention concerne un inimère, et son procédé de fabrication, de formule suivante : dans laquelle X = halogène, nitroxyde, thioester; R = H ou CH3 ; et R' = groupement aliphatique, non aliphatique, linéaire ou ramifié, mésogène, non mésogène, chiral, achiral, hydrocarboné, non hydrocarboné, choisi parmi les substituants fluorocarbone, oligo(oxyéthylène) et siloxane, les groupements alkyle, aryle, mésogène, non mésogène, aliphatique, non aliphatique, siloxane, perfluoroalkyle, perfluoroaryle ou autres groupements fluorocarbone; ainsi que des polymères et leur procédé de fabrication à partir de l'inimère.

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