C - Chemistry – Metallurgy – 01 – B
Patent
C - Chemistry, Metallurgy
01
B
C01B 37/08 (2006.01) C01B 37/02 (2006.01) C01B 37/06 (2006.01)
Patent
CA 2197454
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl)cobalt(III) ion are described. Several types of molecular sieves were prepared using the cobalt metal complex as a template that was shown to be incorporated as a guest molecule within the molecular sieve. Molecular sieves prepared using bis(pentamethylcylclopentadienyl)cobalt(III) ion as template were characterized as having a pore size at least as large as 7 Ä. Other molecular sieves were also prepared using bis(cyclopentadienyl)cobalt(III) templates. The compounds are attractive as catalysts in a wide range of applications.
La présente invention concerne la synthèse et la caractérisation de nouveaux tamis moléculaires à base d'ion di(pentaméthylcyclopentadiényl)cobalt(III). L'utilisation de ce complexe métallique de cobalt, qui s'est trouvé incorporé comme molécule hôte dans le filtre moléculaire, a permis la préparation de différents types de tamis moléculaires. Les tamis moléculaires préparés à partir d'une matrice d'ion di(pentaméthylcyclopentadiényl)cobalt(III) ont été caractérisés comme présentant une dimension des pores atteignant au moins 7 .ANG.. Les matrices di(pentaméthylcyclopentadiényl)cobalt(III) ont également permis la préparation d'autres tamis moléculaires. Ces composés sont intéressants comme catalyseurs dans une large gamme d'applications.
Balkus Kenneth J. Jr.
Gabrielov Alexi G.
Bereskin & Parr
The Board Of Regents Of The University Of Texas System
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