Synthesis of olefins from ketones using...

Details Synthesis of olefins from ketones using... Synthesis of olefins from ketones using...

C - Chemistry, Metallurgy

07

C

260/694, 260/681

C07C 13/19 (2006.01) C07C 1/32 (2006.01) C07C 15/50 (2006.01) C07D 311/58 (2006.01)

Patent

CA 1313199

SYNTHESIS OF OLEFINS FROM KETONES USING BIS(ALKYLCHLOROALUMINO)METHANE ABSTRACT OF THE DISCLOSURE Ketones are methylenated to form the corresponding olefin by reaction with a bis(alkylchloroalumino)methane, e.g., in the form of its dietherate. Examples of ketones which can be methylenated include the cycloalkyl ketones, multi-ring ketones, sterically hindered aliphatic ketones, and aromatic ketones. Yields of from 50-90% can be achieved.

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