Synthesis of vinyl esters

C - Chemistry – Metallurgy – 07 – C

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C07C 69/54 (2006.01) C07C 67/317 (2006.01) C07D 213/63 (2006.01) C07H 13/04 (2006.01)

Patent

CA 2171718

Vinyl ester of an alcohol (such as benzoin) is made by reaction of the alcohol with a 3-haloalkyl acid halide (such as 3-chloropropionyl chloride or bromide) in an anhydrous liquid reaction medium comprising an aprotic solvent (such as toluene) and a hydrogen halide acceptor (such as tertiary amine) at a temperature of at least 20°C.

On prépare un ester de vinyle d'un alcool (tels que de la benzoïne) par réaction de l'alcool avec un halogénure d'acide 3-haloalkyle (tel que du chlorure ou bromure de 3-chloropropionyle) dans un milieu de réaction liquide anhydre comprenant un solvant aprotique (tel que du toluène) ainsi qu'un accepteur d'halogénure d'hydrogène (tel qu'une amine tertiaire) à une température d'au moins 20 DEG C.

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