Synthetic polymer compositions containing charge transfer...

H - Electricity – 01 – B

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H01B 1/12 (2006.01) C07D 339/06 (2006.01) C07D 345/00 (2006.01) C08K 5/45 (2006.01) C08K 5/48 (2006.01)

Patent

CA 2088211

FM/6- 18952/A Synthetic polymer compositions, containing charge transfer complexes, their preparation and the use thereof Abstract of the Disclosure A composition comprising a) a thermosetting, thermoplastic or structurally crosslinked polymer and b) a charge transfer complex of formula I in the form of a network of crystal needles in the polymer matrix [A]? B? (I), wherein A is a compound of formula II or a mixture of compounds of formula II Image (II) wherein the R substituents are identical and are H or C1-C4alkyl, or the adjacent R substituents, taken together, are -(CH2)3- or -(CH2)4-; R1 is H or C1-C4alkyl; and Xl is =N-CN, and X2, X3 and X4 are each independently of one another =0 or =N-CN, and B is a compound of formula III or IIIa Image (III), Image (IIIa), wherein R2, R3, R4 and R5 are each independently of one another H, linear or branched C1-C18alkyl-(Z1)n-, phenyl-(Z1)n- or benzyl-(Z1)n- which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy or C1-C4alkylthio, or R2 and R3 as well as R4 and R5 are together, each independently of the other, trimethylene, tetrarnethylene, -Z2-(CH2)-Z2-, -Z2-(CH2)2-Z2-, -Z1-CH=CH-Z1- or -CH-CH-CH=CH-, each unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy or C1-C4,alkylthio, n is 0 or 1 steht, Y1 and Y2 are each independently of the other -S- or -Se-, Z1 is S- or -Se-, Z2 iS -O-, -S- or -Se-, Z is -S-, -Se- or NR7, and R7 is H, Cl-C6alkcyl, phenyl or benzyl, and R6 is H, C1-C4alkyl, phenyl or benzyl. The composition is an electric conductor.

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