Synthetic porous crystalline material itq-13 its synthesis...

C - Chemistry – Metallurgy – 01 – B

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C01B 37/02 (2006.01) C01B 39/12 (2006.01) C01B 39/48 (2006.01) C01G 1/00 (2006.01)

Patent

CA 2448559

A new synthetic porous crystalline material, designated ITQ-13, is disclosed having, in its calcined form, the X-ray diffraction pattern of Table 2 above. Also disclosed are methods of making ITQ-13 in its silicate and borosilicate forms in the presence of HF using hexamenthonium dihydroxide as a directing agent and hydolyzed tetraethylorthosilicate as a silica source. Aluminum- containing ITQ-13 can be produced by Al exchange of the borosilicate material. ITQ-13 is useful as an acid catalyst and as an adsorbent.

L'invention concerne un nouveau matériau poreux cristallin synthétique, appelé ITQ-13, qui présente, sous sa forme calcinée, le motif de diffraction de rayons X correspondant au Tableau 2 donné dans la description. L'invention concerne également des procédés de production de ITQ-13 sous forme de silicate et de borosilicate, en présence de HF, à l'aide de dihydroxyde d'hexamenthonium, en tant qu'agent directeur, et de tétra-éthylorthosilicate hydrolysé en tant que source de silice. De l'ITQ-13 contenant de l'aluminium peut être produit par échange de Al du matériau borosilicate. L'ITQ-13 peut être utilisé en tant que catalyseur acide et en tant qu'adsorbant.

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