System and process for hydrodesulfurization,...

C - Chemistry – Metallurgy – 10 – G

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C10G 45/08 (2006.01)

Patent

CA 2675825

A method for hydrodesulfurization by forming a dispersion comprising hydrogen-containing gas bubbles with a mean diameter of less than 1 micron dispersed in a liquid phase comprising sulfur-containing compounds. Desulfurizing a liquid stream comprising sulfur-containing compounds by subjecting a fluid mixture comprising hydrogen-containing gas and the liquid to a shear rate greater than 20,000 s-1 to produce a dispersion of hydrogen in a continuous phase of the liquid and introducing the dispersion into a fixed bed hydrodesulfurization reactor from which a reactor product is removed. Systems of apparatus for hydrodesulfurization are also presented.

L'invention concerne un procédé d'hydrodésulfuration par formation d'une dispersion comprenant des bulles de gaz contenant de l'hydrogène, ces bulles possédant un diamètre moyen inférieur à 1 micron dispersées dans une phase liquide comprenant des composés contenant du soufre. La désulfuration d'un flux liquide comprenant des composés contenant du soufre par soumission d'un mélange liquide comprenant un gaz contenant de l'hydrogène et le liquide à un taux de cisaillement supérieur à 20,000 s-1 afin de produire une dispersion d'hydrogène dans une phase continue du liquide et par introduction de la dispersion dans un réacteur d'hydrodésulfuration à lit fixe duquel un produit de réacteur est extrait. L'invention concerne également des système d'appareil d'hydrodésulfuration.

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