T-octyl silicon peroxides

Details T-octyl silicon peroxides T-octyl silicon peroxides

C - Chemistry, Metallurgy

07

F

402/600, 402/9,

C07F 7/08 (2006.01)

Patent

CA 1123853

ABSTRACT OF THE DISCLOSURE A silicon peroxide selected from the formulas: (a) Image (b) Image wherein n is an integer of 1-3; R is a t-octyl group in which a tertiary carbon atom is directly bonded to the peroxy group; and R' is selected from alkyl, phenyl, and alkenyl (provided n is not more than 2), and a carbon chain which forms a saturated heterocyclic ring with the silicon atom, v being an integer equal to the valence of R' and each R' group having up to about 10 carbon atoms. Typical is trimethyl (2,4,4-trimethyl-2-pentylperoxy) silane. These molecules are useful as catalysts for curing polyester resins and are particularly advantageous as crosslinking agents for high density polyethylene in that crosslinking is. effected at lower temperatures than required by the prior art.

324260

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