Techniques for the preparation of highly fluorinated polyethers

C - Chemistry – Metallurgy – 08 – G

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C08G 65/40 (2006.01) C08G 75/23 (2006.01)

Patent

CA 2487649

A process for preparing a fluorinated poly(arylene ether) comprising the repeating unit: formula (I), wherein n provides a molecular weight up to about 30,000 to 100,000, X represents one of following groups: none, ketone, sulfone, sulfide, ether, hexafluoroisopropylidene, .alpha..omega.- perfluoroalkylene, oxadiazole, and Y is 4,4'-(hexafluoroisopropylidene)- diphenyl, 4,4'-isopropylidene diphenyl, 3,3'-isopropylidene diphenyl, phenyl, or chlorinated phenol which process comprises reacting a bis(pentafluorophenyl) compound and a bisphenol or hydroquinone in the presence of a dehydrating agent and a polar aprotic solvent is disclosed. Polymers resulting from the process show good promise as new passive optic polymer waveguide materials.

La présente invention concerne un processus de préparation d'un poly(arylène éther) comprenant l'unité de répétition représentée par la formule (I). Dans cette formule n représente un poids moléculaire compris entre environ 30.000 et 100.000, X représente un des groupes suivants: none, cétone, sulfone, sulfure, éther, hexafluoro-isopropylidène, ?O-perfluoroalkylène, oxadiazole et Y est 4,4'-(hexafluoro-isopropylidéne)-diphényle, 4,4'-isopropylidéne diphényle, 3,3'-isopropylidène diphényle, phényle, ou phénol chloré. Ce processus consiste à faire réagir un composé bi(pentafluorophényle) et un biphénol ou une hydroquinone en présence d'un agent déshydratant et d'un solvant aprotique polaire. Les polymères résultant de ce processus sont très prometteurs comme nouveaux matériaux de guide d'onde polymère optique passif.

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