Tertiary amine catalysts for polyurethanes

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 18/18 (2006.01) B01J 27/24 (2006.01) C07C 217/08 (2006.01) C07D 295/088 (2006.01) C08G 18/20 (2006.01)

Patent

CA 2041480

ABSTRACT The invention pertains to tertiary amines used as catalysts for the preparation of polyurethane foams prepared via the catalytic reaction of a polyisocyanate with a polyol in the presence of blowing agents, etc. The tertiary amine catalysts are prepared by reacting an olefinic nitrile with aliphatic polyol having at least secondary hydroxyl functionality in a ratio less than stoichiometric for providing cyanoalkylated polyol having residual hydroxyl functionality. The resulting cyanoalkylated polyol then is reacted with a secondary amine under conditions for effective reductive alkylation. The tertiary amine catalysts, because of residual secondary hydroxyl functionality, provide for uniform dispersion within a polyurethane formulation; they provide for additional or extended pot life in polyurethane formulations at temperatures below reaction condition, and they are bound by reaction on cure.

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