Thermal cracking process with reduced coking

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 4/06 (2006.01) C10G 9/16 (2006.01)

Patent

CA 2117493

A process for the production of olefins in an olefin plant, which includes an olefin pyrolysis furnace having pyrolysis tubes in which hydrocarbon feedstock is cracked, comprises introducing hydrocarbon feed substantially free of phosphorus-containing compounds into the pyrolysis furnace and operating the furnace under pyrolysis conditions producing olefin-containing effluent therefrom wherein the pyrolysis tubes have an effective passivator of metal catalytic sites bonded to the exposed metal surface by injecting an effective passivator into the furnace at a point above the dew point of water.

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