Thermal disproportionation of organooxysilanes

C - Chemistry – Metallurgy – 07 – F

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C07F 7/18 (2006.01) C07F 7/08 (2006.01)

Patent

CA 2082485

THERMAL DISPROPORTIONATION OF ORGANOOXYSILANES ABSTRACT The present invention is a process for the thermal disproportionation of organooxysilanes containing at least one hydrogen, one organooxy and one cyclic substituent all bonded to a single silicon atom, where the cyclic substituent is selected from a group consisting of aryls, substituted aryls, cycloalkyls and substituted cycloalkyls. The process involves heating the organooxysilanes in a liquid phase to a temperature within a range of about 250°C. to 450°C. The present process is particularly useful for the disproportion- ation of phenyldialkoxysilanes to diphenydialkoxysilanes and cycloalkyldialkoxysilanes to dicyclodialkoxysilanes.

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