Thermooxidative stabilization of polyolefins with a...

C - Chemistry – Metallurgy – 08 – L

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400/9026

C08L 47/00 (2006.01) C08K 5/34 (2006.01) C08L 23/00 (2006.01)

Patent

CA 2019285

1890055 THERMOOXIDATIVE STABILIZATION OF POLYOLEFINS WITH A TRI-SUBSTITUTED-TRIAZINE UV LIGHT STABILIZER AND A PHOSPHOROUS ACID ESTER ABSTRACT OF THE DISCLOSURE Only two symmetrical stabilizers in a polyolefin or copolymer thereof provide thermooxidative or antioxidative stability. One is a phosphite, namely a triaryl phosphite or a pentaerythritol phosphite, symmetrical about the P and C atoms respectively, present in a trace amount, less than 0.1 phr; the other is a tri-substituted triazine derivative ("PIP-T") in which the 2-, 4- and 6-positions of the triazine ring are substituted with a polysubstitut- ed piperazin2-one, piperazine, or piperidine. No other stabilizer such as a hindered phenol antioxidant, is re- quired. Articles thermoformed from the stabilized poly- (alpha-olefin) or copolymer thereof may be used under the hood or the dash of a vehicle, and, in containers for packaging goods, all of which articles are subject to thermooxidative degradation even if they are not subject to ultraviolet light degradation.

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