Thermooxidative stabilization of polyolefins with an...

C - Chemistry – Metallurgy – 08 – K

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C08K 5/00 (2006.01) C08K 5/3492 (2006.01) C08K 5/524 (2006.01) C08K 5/527 (2006.01) C08L 23/02 (2006.01)

Patent

CA 2091462

2091462 9204404 PCTABS00011 Only two symmetrical stabilizers in a polyolefin or copolymer thereof, provide thermooxidative (''TO'') or antioxidative (''AO'') stability. One is a phosphite or fluorophosphite; the other is a monomolecular tri-substituted triazine in which each of three chlorine atoms on a trihalo-s-triazine is substituted with a piperazinone in which the N atom in the 4-position is alkylated. Only a trace amount of phosphite, from 0.01 phr to no more than 0.1 phr, is used; additional phosphite has no noticeable effect. The trace amount of phosphite has a surprising booster effect, giving the stabilized composition excellent TO stability. Articles thermoformed from the stabilized polyolefin or copolymer thereof may be used under the hood or the dash of a vehicle, and, in containers for packaging goods, all of which articles are subject to TO degradation even if they are not subject to ultraviolet light degradation.

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