Thermosetting resin and its production

C - Chemistry – Metallurgy – 09 – D

Patent

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Details

402/297, 402/322

C09D 133/24 (2006.01) C08F 220/58 (2006.01) C08F 246/00 (2006.01)

Patent

CA 1122746

Abstract of the Disclosure A thermosetting resin is disclosed which is a linear copolymer having a molecular weight of 10,000 to 1,000,000 and a glass transition point of -30 to +80°C, obtained by polymerizing in an aqueous medium a monomer mixture ccmprising (1) 0.1 to 50 % by weight of at least one polymerizable monomer having an ampho-ionic structure, selected from the group consisting of (i) compounds representable by the formula: Image [X] wherein Rl is a hydrogen atom or a methyl group, R2 and R3 are the same or different and each represents a Cl-C6 alkyl group, A is 0 or NH, ml and nl are the same or different and each represents an integer of 1 to 12 and X? is SO?, SO? or CO? and (ii) compounds representable by either one of the formulae: Image [II] and Image [III] wherein R4 is a hydrogen atom or a methyl group, R5 is a hydrogen atom or a Cl-C3 alkyl group, m2 is an integer of 0 to 6 and n2 is an integer of 1 to 6, and A and X are as defined above, (2) 0.5 to 70 % by weight of at least one polymerizable monomer containing a reactive amide group, representable by the formula: Image [IV] wherein R6 is a hydrogen atom or a methyl group and R7 is a hydrogen atom or a Cl-C4 alkyl group and (3) l to 99.4 % by weight of at least one of other polymerizable monomers. The resin is useful as the main ingredient of thermosetting paint, in the preparation of molding materials and as a cross-linking agent for polymerizable monomer.

292808

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