Thf intermediates for annonaceous acetogenins

Details Thf intermediates for annonaceous acetogenins Thf intermediates for annonaceous acetogenins

C - Chemistry, Metallurgy

07

D

C07D 307/12 (2006.01) C07D 407/04 (2006.01)

Patent

CA 2318165

Novel tetrahydrofuran-epoxide compounds are described as intermediates for the preparation of non-adjacent bis-THF-acetogenins of pharmaceutical interest. Also described is a novel stereocontrolled synthesis for preparing such intermediates starting with commercially available enantiomers of glycidyl benzylether.

La présente invention concerne de nouveaux composés de tétrahydrofuran-epoxide utilisés comme produits intermédiaires dans la préparation de bis-THF-acétogénine non adjacent ayant un intérêt pharmaceutique. Cette invention concerne par ailleurs une nouvelle synthèse stéréocontrôlée permettant de préparer ces intermédiaires à partir d'énantiomères de benzyléther de glycidyle disponibles dans le commerce.

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