Thiation process

C - Chemistry – Metallurgy – 07 – D

Patent

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Details

260/472.3, 260/5

C07D 498/04 (2006.01) C07D 267/10 (2006.01) C07C 153/05 (1985.01)

Patent

CA 1268762

ABSTRACT THIATION PROCESS The carbonyl group of an amide is thiated to the corresponding thiono group by reacting the amide with phosphorus pentasulfide in the presence of an alkali metal bicarbonate and a hydrocarbon diluent. In pre- ferred embodiments of the invention, the amide is an aromatic amide, and the diluent is an inert hydrocarbon having a boiling point in the range of 50-150°C.

515264

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