Three-liquid-phase epoxidation of perfluoroolefins

Details Three-liquid-phase epoxidation of perfluoroolefins Three-liquid-phase epoxidation of perfluoroolefins

C - Chemistry, Metallurgy

07

D

260/371

C07D 301/03 (2006.01) C07D 303/08 (2006.01) C07D 303/48 (2006.01)

Patent

CA 2023939

TITLE Three-Liquid-Phase Epoxidation of Perfluoroolefins ABSTRACT A process for converting a perfluoroolefin to its epoxide by agitation at reaction conditions that maintain three liquid phases - an aqueous phase containing hypohalite ions, an epoxide phase containing the bulk of the epoxide and essentially no catalyst, a reaction phase comprising an organic liquid in which the a phase transfer catalyst is soluble and in which there is a higher affinity for the perfluoroolefin than for its epoxide (partition coefficient greater than 1.3).

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