Tissue paper containing a vegetable oil based quaternary...

D - Textiles – Paper – 21 – H

Patent

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D21H 17/07 (2006.01) D21H 21/22 (2006.01)

Patent

CA 2263878

Fibrous cellulose materials useful in the manufacture of soft, absorbent paper products such as paper towels, facial tissues, and toilet tissue are disclosed. The paper products contain a vegetable oil based quaternary ammonium chemical softening compound. Examples of preferred vegetable oil based quaternary ammonium chemical softening compounds include diester di(oleyl)dimethyl ammonium chloride (DEDODMAC) (i.e., di(octadec-z-9-eneoyloxyethyl)dimethyl) ammonium chloride) derived from canola oil and/or high oleic safflower oil. Variables that need to be adjusted to maximize the fluidity of vegetable oil based acyl groups include the cis/transisomer ratio or the lodine Value (IV) of the fatty acyl groups. The tissue softness is further enhanced by controlling the purity of the fatty acyl groups and the di-substituted versus mono-substituted long chain hydrocarbyl substitutent ratio in the quaternary ammonium compounds.

Cette invention se rapporte à des matériaux cellulosiques fibreux utiles dans la fabrication de produits en papier doux absorbants, tels que des serviettes de papier, des mouchoirs de papier et du papier hygiénique. Ces produits en papier contiennent un composé d'adoucissage chimique en ammonium quaternaire à base d'huile végétale. Les composés d'adoucissage chimique en ammonium quaternaire à base d'huile végétale préférés sont notamment le chlorure de diester di(oléyl)diméthylammonium (DEDODMAC) (c'est-à-dire le chlorure de di(octadéc-z-9-èneoyloxyéthyl)diméthylammonium)) dérivé d'huile de cholza canola et/ou d'huile de carthame à haute teneur en acide oléique. Les variables qu'il est nécessaire d'ajuster pour maximiser la fluidité des groupes acyle à base d'huile végétale sont notamment le rapport des isomères cis/trans ou l'indice d'iode des groupes acyle gras. On peut encore améliorer la douceur de ces papiers en régulant la pureté des groupes acyle gras et le rapport des substituants hydrocarbyle à chaînes longues di-substitués/mono-substitués dans les composés d'ammonium quaternaire.

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