Titanium-containing finely divided particulate material,...

C - Chemistry – Metallurgy – 01 – G

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C01G 23/053 (2006.01)

Patent

CA 2343085

Disclosed is an amorphous titanium-containing finely divided particulate material. An aqueous sol containing the substance in a concentration of 0.1 to 6.5 mol/l in terms of titanium has a light transmittance of 85% or higher at a wavelength of 450 to 700 nm when the sol has a thickness of 10 nm. The substance generally has an average particle diameter of 0.8 to 50 nm, and gives a thin film having high photocatalytic activity and transparency. The finely particulate substance is obtained by hydrolizing titanium tetrachloride in an aqueous solution in the presence of a specific carboxylic acid, i.e., oxalic acid, citric acid, tartaric acid, malic acid or succinic acid. The sot is useful for coating a substrate such as a lighting appliance to form the thin film. The film exhibits higher transparency than films formed of similar materials known in prior art.

L'invention concerne une substance à fines particules de titane caractérisée en ce qu'une solution aqueuse renfermant ladite substance selon une concentration de titane comprise entre 0,1 et 6,5 mol/l et chauffée jusqu'au point d'ébullition présente un facteur de transmission de la lumière égal ou supérieur à 85 % à une longueur d'onde comprise entre 450 et 700 nm, lorsque la solution a une épaisseur de 10 mm. En règle générale, la substance comporte des particules dont le diamètre moyen va de 0,8 à 50 nm, donnant un film mince à activité catalytique et transparence élevées. Ladite substance est obtenue par hydrolyse de tétrachlorure de titane dans une solution aqueuse, en présence d'acide carboxylique.

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