Titanocenes and a radiation-polymerizable composition...

C - Chemistry – Metallurgy – 07 – F

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96/89, 400/9015,

C07F 7/28 (2006.01) C07F 17/00 (2006.01) C08F 2/50 (2006.01) G03F 7/029 (2006.01) G03F 7/031 (2006.01)

Patent

CA 1332952

Titanocenes with .pi.-cyclopentadienyl ligands, in which one or two carbocyclic or heterocyclic aromatic rings are bonded to the metal, the aromatic rings being substi- tuted in at least one of the two ortho-positions relative to the metal-carbon bonds by CF2Z (Z = F or substituted or unsubstituted alkyl), are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated com- pounds. They are distinguished by a high radiation sensi- tivity, stability to air and thermal effects, and high effectiveness in the range from UV light to visible light.

497984

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