Transition metal-based ceramic material and articles...

C - Chemistry – Metallurgy – 01 – B

Patent

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C01B 21/06 (2006.01) H01M 4/38 (2006.01) H01M 4/02 (2006.01) H01M 4/58 (2006.01) H01M 10/40 (2006.01)

Patent

CA 2308613

A non-oxide, transition metal-based ceramic material has the general formula AyM2Zx, wherein A is a group IA element, M is a transition metal and Z is selected from the group consisting of N, C, B, Si, and combinations thereof, and wherein x 2 and y 6-x. In these materials, the group IA element occupies interstitial sites in the metallic lattice, and may be readily inserted into or released therefrom. The materials may be used as catalysts and as electrodes. Also disclosed herein are methods for the fabrication of the mates.

Ce matériau céramique, à base de métal de transition non-oxyde, correspond à la formule générale: A¿y?M¿2?Z¿x? dans laquelle A représente un élément du groupe IA, M représente un métal de transition et Z est issu du groupe constitué de N, C, B, Si et de leurs combinaisons, la valeur de x étant inférieure ou égale à 2 et celle de y inférieure ou égale à 6-x. Dans ces céramiques, l'élément du groupe IA occupe dans la trame métallique des sites interstitiels et peut facilement y être introduit ou en être retiré. Il est possible d'utiliser ces matériaux céramiques comme catalyseurs et électrodes. L'invention porte également sur des procédés de fabrication de mattes.

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