Transition metal carbonyl complexes intercalated with...

Details Transition metal carbonyl complexes intercalated with... Transition metal carbonyl complexes intercalated with...

C - Chemistry, Metallurgy

07

C

23/27, 252/52, 2

C07C 47/02 (2006.01) B01J 31/20 (2006.01) C01B 31/00 (2006.01) C10K 3/04 (2006.01)

Patent

CA 1169840

ABSTRACT OF THE DISCLOSURE Transition metal carbonyl clusters intercalated with lamellar material such as graphite or smectites are prepared by reacting an intercalate of a transition metal halide with carbon monoxide at elevated temperature and at ambient to superatmospheric pressure. The intercalated complexes are useful in the catalysis of a variety of organic reactions including the water gas shift reaction, hydrogenation, hydroformylation, methanation, and so forth.

388030

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