Transition metal complexes with proton sponges as ligands

Details Transition metal complexes with proton sponges as ligands Transition metal complexes with proton sponges as ligands

C - Chemistry, Metallurgy

07

F

C07F 13/00 (2006.01) A61K 33/24 (2006.01) A61P 35/00 (2006.01) B01J 31/18 (2006.01) C07B 37/04 (2006.01) C07B 41/02 (2006.01) C07B 43/04 (2006.01) C07C 67/293 (2006.01) C07F 15/00 (2006.01)

Patent

CA 2435773

Transition metal complexes with chino[7,8-h]chinolines and cyclopentadieno[1,2- h: 4,3-h']dichinolines as proton sponge ligands and method for the production thereof. Said complexes are suitable as catalysts e.g. palladium complexes for a Heck reaction and for amination and C-H activation reactions. The platinum and palladium complexes are potentially good cytostatics.

L'invention concerne des complexes de métal de transition, comportant des chino[7,8-h]chinolines et des cyclo-pentadiène[1,2-h : 4,3-h']dichinolines en tant que ligands éponges à protons. La présente invention porte également sur un procédé de production de ces complexes, qui servent de catalyseurs, par exemple, les complexes de palladium pour la réaction de Heck, ainsi que pour les réactions d'activation C-H et d'amination. Les complexes de platine et de palladium sont potentiellement des cytostatiques efficaces.

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