Transition-metal compound having a bis-substituted-...

C - Chemistry – Metallurgy – 07 – F

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C07F 17/00 (2006.01) B01J 31/22 (2006.01) C08F 10/00 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 1326676

ABSTRACT OF THE DISCLOSURE A novel transition-metal compound having a bis- substituted cyclopentadienyl ligand of bridged structure (I) and a novel mixture of the compound (I) with an aluminoxane (B), each useful as catalyst com- ponent(s) for stereoregular olefin polymerization are provided, which compound (I) is expressed by the formula Image ( I ) wherein M is Zr or Hf; Y is Si or Ge; R1-C5H4-n and R1q-C5H4-q each represent an unsubstituted or substituted cyclopentadienyl group; n and q each represent an integer of 0 to 4, but cases of n=q=0 and n=q=4 are excluded; R1s may be same or different and each represent H, silyl or hydrocarbon radical; R2s may be same or different and represent H or hydrocarbon radical; and X s may be same or different and represent H, halogen or hydrocarbon radical; and which aluminoxane is expressed by the formula (II) or the formula (III) Image ??? [ II ] Image ??? [ III ] wherein m represents an integer of 4 to 30 and R3 represents a hydrocarbon radical.

582530

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