Transition metal olefin polymerization catalyst having...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/60 (2006.01) C08F 4/70 (2006.01) C08F 10/00 (2006.01) C08F 4/6192 (2006.01) C08F 110/02 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2418993

This invention is directed to cationic polymerization of olefins using catalysts comprising a Group 3, 4, 5, 6, 8, or 10 transition metal cation composition wherein at least one ligand coordinated to the transition metal is a cyclopropenyl moiety. The neutral transition metal compound catalyst precursor is activated to a catalyst state by exposure to an activator composition which may be any of the heretofore known activator compositions such as alumoxane or a compatible non-coordinating anion (NCA).

L'invention porte sur la polymérisation cationique d'oléfines à l'aide de catalyseurs comportant une composition de cations d'un métal de transition des groupes 3, 4, 5, 6, 8, ou 10 dans laquelle l'un au moins des ligands coordonnés au métal de transition est un fragment de cyclopropényle. Un composé neutre précurseur de catalyseur de métal de transition est porté à l'état de catalyseur par exposition à une composition activatrice qui peut être l'une des compositions activatrices déjà connues telles que l'alumoxane ou un anion non coordinateur (NCA) compatible.

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