Transition metal sulfide promoted molybdenum or tungsten...

C - Chemistry – Metallurgy – 10 – G

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196/54, 252/53.A

C10G 45/08 (2006.01) B01J 27/047 (2006.01) B01J 37/20 (2006.01) C10G 45/04 (2006.01) C10G 45/50 (2006.01)

Patent

CA 1251195

ABSTRACT OF THE DISCLOSURE Hydrocarbon feeds are upgraded by contacting a feed, at elevated temperature and in the presence of hydrogen, with a self-promoted catalyst prepared by heating one or more catalyst precursors under oxygen- free conditions in the presence of sulfur at a temperature of at least about 150°C. The catalyst pre- cursors will be one or more compounds of the formula (ML)(MoyW1-yS4) wherein M comprises one or more di- valent promoter metals selected from the group con- sisting of Ni, Co, Zn, Cu and mixtures thereof, wherein y is any value ranging from 0 to 1 and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating, polydentate ligand.

491752

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