Transition metal tris-dithiolene and related complexes as...

Details Transition metal tris-dithiolene and related complexes as... Transition metal tris-dithiolene and related complexes as...

B - Operations, Transporting

01

J

196/132, 252/93.

B01J 31/12 (2006.01) B01J 27/04 (2006.01) B01J 31/22 (2006.01) C10G 45/04 (2006.01)

Patent

CA 2020092

ABSTRACT OF THE DISCLOSURE The present invention is based on the discovery that certain transition metal containing complexes thermally decompose to form solids contain- ing the transition metal, sulfur and carbon and that these transition metal, sulfur and carbon containing solids are particularly suitable as catalysts for hydrodesulfurization, hydrodenitrogenation and aromat- ics hydrogenation. The transition metal complexes that are thermally decomposed to novel catalysts are complexes of the type represented by the general formula MLn3, wherein M is selected from Mo, W, Re and mixtures thereof, L is a dithiolene or aminobenzene- thiolate ligand, and n represents the total charge of the metal complexes, and is 0, -1, or -2.

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