Triazine-containing multisilane coupling agents for coating...

C - Chemistry – Metallurgy – 07 – F

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117/213, 400/703

C07F 7/18 (2006.01) C03C 25/40 (2006.01) C08J 5/08 (2006.01) C08K 5/54 (2006.01) C08K 5/544 (2006.01) C08K 9/06 (2006.01) C08L 27/06 (2006.01) C09J 175/04 (2006.01)

Patent

CA 1335993

At least three, and as many as eighteen, most prefer- ably at least nine, crosslinking sites are provided through the alkoxy groups in multiple chains on a triazine ring (hence "multisilane"), on a single molecule of the multisilane. The multisilane, useful as a coupling agent, is formed by reacting a triazine-containing compound with a suitable aminoalkyl-alkoxoysilane, or, alkyl-aminoalkyl- alkoxysilane in either an anhydrous, or an aqueous liquid medium. A size containing the multisilane, enhances the reinforced properties of organic synthetic resinous mater- ials in which the fibers are used, and most particularly those of rigid poly(vinyl chloride) (PVC) with which it provides cohesive bonding of glass fiber surfaces. Glass fibers coated with a basic film former and the multisilane are covalently bonded on the one hand through some of at least nine alkoxy groups on each of the multisilane mole- cules, to Si atoms of a glass surface, and on the other hand, through at least some of the amine groups on each of the molecules, to the vinyl chloride (VC) resin in a reaction which involves allylic chloride bonds in the VC resin. The multisilane is effective in adhesives for a wide variety of materials, and in protective coatings.

591795

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