Trichlorophloroglucinol tripropylether,...

C - Chemistry – Metallurgy – 07 – C

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C07C 39/10 (2006.01) C07C 37/02 (2006.01) C07C 37/055 (2006.01) C07C 37/64 (2006.01) C07C 43/225 (2006.01)

Patent

CA 1149821

ABSTRACT OF THE DISCLOSURE Two novel compounds, trichlorophloroglucinol tripropyl- ether and trichlorophloroglucinol triisopropylether are disclosed, as well as the process for their preparation and for their hydro- lysis to form trichlorophloroglucinol. A process for their preparation comprises reacting hexachlorobenzene with sodium propylate or sodium isopropylate, in a molar ratio of about 1:3 to about 1:20, respectively, in an aprotic solvent, at a temperature from about 50 to about 250°C. The process for the preparation of the trichlorophloroglucinol comprises hydrolizing trichlorophloro- glucinol tripropylether or trichlorophloroglucinol triisopropyl- ether to form trichlorophloroglucinol.

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