Tricyclic heterocyclic sulfonamide and sulfonic ester...

C - Chemistry – Metallurgy – 07 – D

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C07D 279/20 (2006.01) A61K 31/395 (2006.01) C07C 211/55 (2006.01) C07C 229/58 (2006.01) C07C 311/29 (2006.01) C07D 209/88 (2006.01) C07D 219/04 (2006.01) C07D 219/06 (2006.01) C07D 219/08 (2006.01) C07D 221/12 (2006.01) C07D 223/22 (2006.01) C07D 243/38 (2006.01) C07D 265/38 (2006.01) C07D 267/18 (2006.01) C07D 267/20 (2006.01) C07D 281/14 (2006.01) C07D 413/12 (2006.01) C07D 498/04 (2006.01) C07D 513/04 (2006.01) C07F 7/18 (2006.01)

Patent

CA 2144854

Novel tricyclic heterocyclic sulfonamide derivatives and sulfonic ester derivatives which have each an antitumor action and are represented by the following general formula (I) and processes for producing the same are provided. These compounds have each an excellent antitumor activity. A sulfonamide derivative or a sulfonic ester derivative represented by the following general formula (I): Image (I) {G represents an aromatic 5- or 6-membered ring; L represents O or -N(R1)- (R1 represents hydrogen or lower alkyl); and M represents a tricyclic structure selected from among the following ones; Image Image Image (a) (b) (c) Image Image Image (d) (e) (f) [rings A and B represent each an unsaturated 5- or 6-membered ring; X represents N(R2), (wherein R2 represents hydrogen or lower alkyl), or NHCO; Y represents O, S(O)n, C(R3)(R4), C(O), N(R5), CH(R6)CH(R7). C(R8)=C(R9), N(R10)C(O), N=C(R11), OCH(R12), S(O)nCH(R13) or N(R14)CH(R15); Z represents nitrogen or C(R16); (n represents 0, 1 or 2, R3 to R13, R15 and R16 each represents hydrogen or lower alkyl, and R14 represents hydrogen, lower alkyl or lower acyl.)]} - 105 -

L'invention concerne des dérivés de sulfamide et d'ester sulfonique comportant un hétérocycle tricyclique, représentés par la formule générale (I) ainsi que son procédé de production, formule dans laquelle G représente un cycle aromatique à 5 ou 6 éléments; L représente O ou NR<1>, R<1> représentant hydrogène ou alkyle inférieur; et M représente une structure tricyclique choisie parmi les éléments suivants (a), (b), (c), (d), (e), (f), dans lesquels les cycles A et B représentent chacun un cycle insaturé à 5 ou 6 éléments; X représente NR<2> (R<2> représentant hydrogène ou alkyle inférieur) ou NHCO; Y représente O, S(O)n, CR<3>R<4>, CO, NR<5>, CHR<6>CHR<7>, CR<8>=CR<9>, NR<10>CO, N=CR<11>, OCHR<12>, S(O)nCHR<13> ou NR<14>CHR<15>; et Z représente N ou CR<16>, n correspondant à 0, 1 ou 2; R<3>-R<13>, R<15> et R<16> représentent chacun hydrogène ou alkyle inférieur; et R<14> représente hydrogène, alkyle inférieur ou acyle inférieur.

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