Tris(pentafluorophenyl)borane complexes and catalysts...

C - Chemistry – Metallurgy – 07 – F

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C07F 5/02 (2006.01) C07F 7/08 (2006.01) C07F 7/18 (2006.01) C07F 9/54 (2006.01) C07F 17/00 (2006.01) C08F 4/643 (2006.01) C08F 10/00 (2006.01) C08F 10/14 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01) C08F 110/02 (2006.01) C08F 110/14 (2006.01) C08F 210/14 (2006.01)

Patent

CA 2132206

2132206 9321238 PCTABS00027 Tris(pentafluorophenyl)borane complexes having the general formula (C6F5)3B.(YXH)q wherein X is oxygen, or sulfur; q is 1 to 3; Y is a hydrogen atom, R1-, (R2)3Si, or (R3)2C=N-; R1 is a hydrocarbyl group containing 1 to 500 carbon atoms, and may contain a divalent oxygen and further may be a fluorine-containing hydrocarbyl group; R2 is independently a linear or branched alkyl group containing 1 to 25 carbon atoms, or a phenyl group, further R2 may contain a SiO- group; and R3 is independently a hydrocarbyl group containing 1 to 25 carbon atoms, R3 may be a hydrogen atom provided both R3 groups selected are not hydrogen atoms; and to complexes containing the borane complexes with an organometallic compound, either as a neutral compound or as an acidic salt that are useful as catalysts for polymerization and copolymerization of olefins and to polymeric products prepared using these catalysts.

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