Trisaryl-1,3,5-triazine ultraviolet light absorbers...

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 251/00 (2006.01) C07D 251/24 (2006.01)

Patent

CA 2333324

This invention relates generally to hindered phenol-substituted triazines and the use thereof to protect materials such as coatings, polymers, resins, organic compounds and the like against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants and combinations thereof. The new class of hindered phenol-substituted triazines includes a trisaryl-1,3,5-triazine in which one of the aryl groups is substituted by a group which comprises a hindered phenol or is a hindered phenol and is further substituted by a hydroxyl group, either free or blocked to form a latent stabilizer, ortho- to the point of attachment to the triazine. These materials may, under the appropriate circumstances, form oligomers. A method for stabilizing a material by incorporating such hindered phenol-substituted triazines is also disclosed.

La présente invention concerne en général des triazines substituées avec phénols bloqués qui permettent de protéger notamment des revêtements, des polymères, des résines, des composés organiques et analogues contre des dégradations liées aux conditions ambiantes telles que rayonnement ultraviolet, radiation actinique, oxydation, humidité, polluants atmosphériques, seules ou combinées. La nouvelle classe de triazines substituées à phénols bloqués comprend une trisaryl-1,3,5-triazine dans laquelle un des groupes aryle est substitué par un groupe qui renferme un phénol bloqué ou qui est lui-même un phénol bloqué et qui, de plus, est substitué par un groupe hydroxy, soit libre soit bloqué pour former un stabilisateur latent, en position ortho- au point de rattachement à la triazine. Ces matériaux peuvent, dans certaines circonstances, former des oligomères. L'invention concerne également un procédé de stabilisation d'un matériau par incorporation desdites triazines substituées avec phénols bloqués.

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