Trivalent metal salts of dodecametal triaconta carbonyls

Details Trivalent metal salts of dodecametal triaconta carbonyls Trivalent metal salts of dodecametal triaconta carbonyls

C - Chemistry, Metallurgy

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C01G 55/00 (2006.01) B01J 31/20 (2006.01) C01G 1/04 (2006.01) C07C 29/157 (2006.01) C07C 29/158 (2006.01) C07C 31/00 (2006.01)

Patent

CA 1045336

TRIVALENT METAL SALTS OF DODECAMETAL TRIACONTA CARBONYLS ABSTRACT OF THE INVENTION This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula: M2[TyT'12-y (CO)30]3 wherein M is a divalent metal cation which is one of aluminum, gallium, iridium, scandium, yttrium, and rhenium, T and T' are each different metals selected from the group consisting of cobalt, iridium and rhodium, and y may be any whole number between 1 and 11. These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to pro- duce oxygenated compounds such as methanol, ethylene glyccl, glycerine and 1, 2-propylene glycol. S P E C I F I C A T I O N -1-

221170

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