C - Chemistry – Metallurgy – 22 – B
Patent
C - Chemistry, Metallurgy
22
B
53/148
C22B 3/06 (2006.01) C22B 3/16 (2006.01) C22B 7/00 (2006.01) C22B 34/36 (2006.01)
Patent
CA 1279994
ABSTRACT Improvements in Tungsten Recovery The scarcity of high grade tungsten ores obliges users to seek to recover it from scrap materials, but drill bits in particular pose especial problems. Existing proposals to use acidic hydrogen peroxide to oxidise and solubilise tungsten are extremely inefficient in reagent consumption per unit tungsten recovered. According to the present invention hydrogen peroxide can be used considerably more efficiently with sub-stoichiometric reagent addition per stage, especially from 6 to 12 stages and by the use of a small amount of certain promoters which it is believed may form a water-soluble complex with tungsten which provides an alternative route for tungsten dissolution. Many of the promoters are aromatic hydroxyl or amino acids such as 2-hydroxybenzoic acid, 2-aminobenzoic acid, 4-hydroxybenzene-phenol and its related oxidation products such as 1,4-benzoquinone. Also, certain aliphatic acids such as tartaric and epoxy succinic acid show some promotional activity.
504950
Riches Mckenzie & Herbert Llp
Solvay Interox Limited
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