Two-dimensional quadrupole ion trap operated as a mass...

H - Electricity – 01 – J

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H01J 49/00 (2006.01) H01J 49/42 (2006.01)

Patent

CA 2474857

A three section linear or two-dimensional (2D) quadrupole ion trap as a high performance mass spectrometer is described. Mass analysis is performed by ejecting ions radically out a slot formed in one of the rods using the mass selective instability mode of operation. The slot geometry is optimized to yield high ejection efficiencies. Resolution can be controlled by using appropriate end section potentials to control the axial spread of the ion cloud. Multiple detectors can be used for enhancing sensitivity and for enabling enhanced ion analysis techniques in the ion trap.

L'invention a trait à un piège à ions quadripolaire à trois sections linéaire ou bidimensionnel, utilisé comme spectromètre de masse haute performance. L'analyse de masse est réalisée par l'éjection d'ions de façon radicale depuis une rainure formée dans l'une des tiges, en mode de fonctionnement à instabilité sélective de masse. La géométrie des rainures est optimisée de façon que soit assurée une efficacité d'éjection élevée. La résolution peut être commandée au moyen de potentiels de sections d'extrémité appropriés, afin que soit régulée la dispersion axiale du nuage d'ions. Il est possible d'utiliser des détecteurs multiples pour améliorer la sensibilité et permettre la mise en oeuvre de techniques d'analyse d'ions améliorées dans le piège à ions.

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