Upgrading synthesis gas

B - Operations – Transporting – 01 – J

Patent

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252/53.C, 260/63

B01J 27/24 (2006.01) B01J 23/70 (2006.01) B01J 23/89 (2006.01) C07C 1/04 (2006.01) C07C 9/00 (2006.01) C07C 27/06 (2006.01) C07C 29/157 (2006.01) C07C 29/158 (2006.01) C07C 31/04 (2006.01) C07C 31/08 (2006.01) C07C 51/10 (2006.01)

Patent

CA 1195678

ABSTRACT A process is provided for the upgrading of synthesis gas to hydrocarbons and oxygenated hydrocarbons, particularly olefins and carboxylic acids by contacting synthesis gas with catalysts comprising the mixed oxides of ruthenium, copper, an alkali or alkaline earth metal, and optionally a metal selected from Ce, Cr, Fe, Mn, Mo, Th, Zn or mixtures thereof. The synthesis gas upgrading product may be contacted with a hydrogenation catalyst to provide alkanes, alcohols and esters, useful for fuels. Catalysts comprising the mixed oxides of ruthenium, copper, at least one alkali metal and at least one of rhodium, iridium, palladium, and platinum are further provided which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.

416328

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