Use of a high purity imidazoline based amphoacetate...

E - Fixed Constructions – 21 – B

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E21B 43/22 (2006.01) C09K 8/38 (2006.01) C09K 8/594 (2006.01) C09K 8/94 (2006.01)

Patent

CA 2222775

Increased foam quality and resistance to hydrocarbon defoaming for foams used in well boring and stimulation processes as well as secondary and tertiary oil recovery is obtained using imidazoline-based amphoacetates of higher purity, containing essentially negligible amounts of unalkylated amido amines, lower amounts of glycolic acid salts and monochloroacetate salts. The higher purity amphoacetates can be obtained via processes utilizing precise pH control during the reaction of imidazoline, or its open-chain derivatives, with alkylating agents, e.g. sodium monochloroacetate. Thse higher-purity amphoacetates contain essentially fully alkylated products and lower amounts of glycolic acid derivatives, even though a ratio of monohaloalkylate to substituted imidazoline, or its open-ring derivative, of less than 1.5:1.0 and close to 1.0:1.0 is used.

L'utilisation d'amphoacétates à base d'imidazoline de plus grande pureté, contenant essentiellement des amidoamines non alkylées en quantité négligeable et des quantités moindres de sels d'acide glycolique et de sels de monochloroacétate permet d'obtenir une mousse de meilleure qualité et plus résistante au démoussage d'hydrocarbures. Ce type de mousse est destiné au forage de puits et aux traitements de stimulation ainsi qu'à la récupération secondaire et la récupération tertiaire de pétrole. Les amphoacétates de plus grande pureté sont obtenus grâce à des traitements dans lesquels on effectue une régulation précise du pH pendant la phase de réaction de l'imidazoline, ou de ses dérivés à chaîne ouverte, avec des agents d'alkylation, tels que, par exemple, le monochloracétate de sodium. Ces amphoacétates de plus grande pureté contiennent essentiellement des produits entièrement alkylés et des quantités moindres de dérivés d'acide glycolique, malgré l'utilisation d'un rapport du monohalokylate à l'imidazoline substituée, ou à son dérivé à cycle ouvert, inférieur à 1,5:1,0 et proche de 1,0:1,0.

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